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The same current is passed for the same time through solutions of AgNO3 and CuSO4 ...

The same current is passed for the same time through solutions of AgNO3 and CuSO4 connected in series. How much silver will be deposited if 1.0 g of copper is produced?
[Cu = 63.5, S = 32, O = 16, Ag = 108, N = 14]
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  • A 1.7 g
  • B 3.4 g
  • C 6. 8 g
  • D 13. 6 g
Correct Answer: Option B
Explanation:
From Faraday;s second law of electrolysis
\(\frac{\text{Mass of silver deposited}}{\text{Mass of copper deposited}}\) = \(\frac{\text{Equivalent mass of silver}}{\text{Equivalent mass of copper}}\)
\(\frac{\text{Mass of silver deposited}}{1.0g}\) = \(\frac{108}{63.5}\)
= 31.75g
Copper is devalent = Cu2+
Mass of silver deposited = \(\frac{108g}{31.75g}\)
= 3.30g

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