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The curve above represents the solubility curve of \(KClO _{3}\). The number of moles ...

The curve above represents the solubility curve of \(KClO _{3}\). The number of moles of \(KClO _{3}\) crystals produced by cooling \(200 cm ^{3}\) of a saturated solution of the salt from \(65^{\circ} C\) to \(25^{\circ} C\) is ____________
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  • A \(6.30 mol\)
  • B \(1.26\) mole
  • C \(0.63\) mole
  • D \(7.30\) mole
Correct Answer: Option B
Explanation:
From the graph, solubility of \(KClO _{3}\) at \(65^{\circ} C \Longrightarrow 6 moldm ^{-3}\),
that at \(25^{\circ} C =1\) moldm \(^{-3}\)
Mole present in solution at \(65^{\circ} C\)
\(=\left(\frac{6 \times 20}{100}\right) \Rightarrow 1.2\) mole
Mole present in solution at \(25^{\circ} C\)
\begin{aligned}
&=\left(\frac{1 \times 200}{1000}\right) \Rightarrow 0.2 \text { mole } \\
&\text { Precipitate }=1.2 mole -0.2 \text { mole } \\
&\Rightarrow \text { 1mole }
\end{aligned}

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