Chemistry Past Questions and Answers

Consider the reaction represented by the equation: 2SO\(_{2(g)}\) + O\(_{2(g)}\) 2SO\(_{3(g)}\). \(\Delta\)H = 188KJ.
(a) Write an expression for the equilibrium constant
(b) Sketch an energy diagram for the forward reaction, showing the profile for the catalyzed and non-catalyzed systems.
(c) state the reason, the effect of the following on the position of equilibrium of the system:
(i) increase in temperature
(ii) increase in pressure;
(iii) removal of some of the SO\(_3\) produced;
(iv) presence of V\(_2\)O\(_5\)
(d)(i) Write equations to show how the sulphur(VI) oxide is converted to tetraoxosulphate(VI) acid in the contact process
(ii) Give two uses of tetraoxosulphate(VI) acid.

(a)(i) Define the term addition polymerization
(ii) What type of organic compounds undergo addition polymerization
(iii) List two factors which affect the strength of polymers

(b) The diagram below shows some reaction pathways involving ethanol

(i) Write the name and structural of the organic product X
(ii) State the reagent for the conversation indicated as step A.
(iii) What type of reaction will ethanol undergo CH\(_3\)CH\(_2\)COOH during the process of conversation indicated as step B?

(c)(i) Write three balanced equation for the complete combustion of ethanol in :date the volume of oxygen required at s.t.p for the complete combustion of ethanol. (H = 1, C = 12, O = 16, molar volume of gases at s.t.p. = 22.4 dm\(^3\))

(d)( i} State two substances produced when coal is heated in the absence of air
(ii) What name is given to the process in (d)(i) above?
(iii) State the importance of the non-volatile residue of the process named in (d)(iii) to the iron and steel industry.

The metal extracted from cassiterite is

The metal extracted from cassiterite is

In which of the following is the oxidation number of nitrogen zero?